By J.?M. Lehn(eds.)
This publication covers significant periods of crystals within the layout of novel fabrics, with an emphasis on advances and applications.
* The editor is without doubt one of the pioneers within the "design" and "engineering" procedure in sturdy country supramolecular chemistry
* All authors constructed a particular classification of crystals and are global leaders within the field
* displays the speedy development made during this fieldContent:
Chapter 1 Hydrogen Bonds in Inorganic Chemistry: program to Crystal layout (pages 1–75): Lee Brammer
Chapter 2 Molecular attractiveness and Self?Assembly among Amines and Alcohols (Supraminols) (pages 77–151): Raffaele Saladino and Stephen Hanessian
Chapter three Very huge Supramolecular pills in response to Hydrogen Bonding (pages 153–175): Jerry L. Atwood, Leonard J. Barbour and Agoston Jerga
Chapter four Molecular Tectonics: Molecular Networks in keeping with Inclusion techniques (pages 177–209): Julien Martz, Ernest Graf, Andre De Cian and Mir Wais Hosseini
Chapter five Layered fabrics by way of layout: 2nd Coordination Polymeric Networks Containing huge Cavities/Channels (pages 211–239): Kumar Biradha and Makoto Fujita
Chapter 6 the development of One?, ? and Three?Dimensional Organic–Inorganic Hybrid fabrics from Molecular construction Blocks (pages 241–274): Robert C. Finn, Eric Burkholder and Jon A. Zubieta
Chapter 7 A Rational process for the Self?Assembly of Molecular construction Blocks within the box of Molecule?Based Magnetism (pages 275–323): Melanie Pilkington and Silvio Decurtins
Chapter eight Polymorphism, Crystal variations and Gas–Solid Reactions (pages 325–373): Dario Braga and Fabrizia Grepioni
Chapter nine Solid–Gas Interactions among Small Gaseous Molecules and Transition Metals within the good nation. towards Sensor purposes (pages 375–386): Michel D. Meijer, Robertus J. M. Klein Gebbink and Gerard van Koten
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Additional resources for Crystal Design: Structure and Function, Volume 7
The building blocks resemble XXVII, but with hydrogen bonds to six neighbouring units in directions approximately orthogonal to phenanthroline planes. Functionalized terpyridine (terpy-NH) ligands have also been used to prepare 2D hydrogen-bonded grids from [M(terpy-NH)2 ]2 (M Co, Zn) building blocks similar to XXXI  (Figure 25). However, the use of different counterions, PF6 À , BF4 À or CF3 SO3 À , results in changes from 2D interwoven grids to a 1D tape, owing to different numbers of potential hydrogen bonding sites being used in formation of the crystalline assembly.
All form structures based upon ribbon motifs containing NH Á Á Á (Cl)2 Á Á Á HN interactions, into which synthon I can be accommodated, but is not required. These hydrogen-bonded salts show distinct potential for the controlled design of new crystalline structures, and are applicable to incorporation of a wide variety of transition metal and main group metal ions. 2 and 7). Finally, it should be noted that there are many examples, some designed deliberately , in which ligands bearing peripheral hydrogen bond donor groups have been coordinated to metals that bear a halide (often chloride) ligand, resulting in a 1D hydrogen-bonded tape .
1±12 (2001). Reproduced by permission of the Royal Society of Chemistry. 46 Crystal Design: Structure and Function X− M b 2+ a + R -N H 3 c (a) a (b) Figure 36 Two hydrogen bonding schemes typically observed in inorganic±organic perovskite structures of empirical formula (RNH3 )2 [MX4 ] and (H3 NRNH3 )[MX4 ]. (a) NH 3 group forms two N±H Á Á Á X hydrogen bonds to bridging halides and one to a terminal halide.
Crystal Design: Structure and Function, Volume 7 by J.?M. Lehn(eds.)