Download PDF by : Acyl Halides (1972)

ISBN-10: 0470771275

ISBN-13: 9780470771273

ISBN-10: 0471669369

ISBN-13: 9780471669364

Content:
Chapter 1 common and theoretical features (pages 1–34): Massimo Simonetta and Paolo Beltrame
Chapter 2 education of acyl halides (pages 35–68): Martin F. Ansell
Chapter three Detection, selection and characterization (pages 69–101): Hannah Weiler?Feilchenfeld
Chapter four Acid?base behaviour and intricate formation (pages 103–136): D. P. N. Satchell and R. S. Satchell
Chapter five Directing and activating results of COX teams (pages 137–176): P. H. Gore
Chapter 6 Mechanisms of substitution on the COX staff (pages 177–230): Antti Kivinen
Chapter 7 aid (pages 231–251): Owen H. Wheeler
Chapter eight Rearrangements concerning acyl halides (pages 253–292): D. V. Banthorpe and B. V. Smith
Chapter nine Photochemistry and radiation chemistry of carbonyl halides (pages 293–312): U. Schmidt and H. Egger
Chapter 10 organic reactions of carbonyl halides (pages 313–348): Sasson Cohen
Chapter eleven Thiocarbonyl halides (pages 349–380): okay. T. Potts and C. Sapino
Chapter 12 Chloroformate esters and similar compounds (pages 381–453): Dennis N. Kevill
Chapter thirteen The acyl hypohalites (pages 455–500): Dennis D. Tanner and Nigel J. Bunce

Show description

ISBN-10: 0470771275

ISBN-13: 9780470771273

ISBN-10: 0471669369

ISBN-13: 9780471669364

Content:
Chapter 1 common and theoretical features (pages 1–34): Massimo Simonetta and Paolo Beltrame
Chapter 2 education of acyl halides (pages 35–68): Martin F. Ansell
Chapter three Detection, selection and characterization (pages 69–101): Hannah Weiler?Feilchenfeld
Chapter four Acid?base behaviour and intricate formation (pages 103–136): D. P. N. Satchell and R. S. Satchell
Chapter five Directing and activating results of COX teams (pages 137–176): P. H. Gore
Chapter 6 Mechanisms of substitution on the COX staff (pages 177–230): Antti Kivinen
Chapter 7 aid (pages 231–251): Owen H. Wheeler
Chapter eight Rearrangements concerning acyl halides (pages 253–292): D. V. Banthorpe and B. V. Smith
Chapter nine Photochemistry and radiation chemistry of carbonyl halides (pages 293–312): U. Schmidt and H. Egger
Chapter 10 organic reactions of carbonyl halides (pages 313–348): Sasson Cohen
Chapter eleven Thiocarbonyl halides (pages 349–380): okay. T. Potts and C. Sapino
Chapter 12 Chloroformate esters and similar compounds (pages 381–453): Dennis N. Kevill
Chapter thirteen The acyl hypohalites (pages 455–500): Dennis D. Tanner and Nigel J. Bunce

Show description

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Additional resources for Acyl Halides (1972)

Example text

2 . Preparation of acyl halides C. With Modified Phosphorus Halides 43 As an alternative to the phosphorus halides catechylphosphotrichloride4* (2;X= Cl) or t r i b r ~ m i d e(2; ~ ~X = Br) may 5e used to convert carboxylic acids or anhydrides into the corresponding acyl halide. p. p. 132"/13 mm), is commercially available, but may be easily prepared from catechol and phosphorus pentachloride. p. 121"/13 mm). For the preparation of the bromides the following procedure Is given49: a solution of equimolar quantities of the acid (or anhydride) and catechylphosphomonobromide in methylene chloride is treated at 0" with an equimolar amount of bromine, then warmed to 100" and distilled.

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32, 1289, 1296 (1960). 70. E. Catalan0 and K. S . Pitzer, J. Ant. Clieni. ,80, 1054 (1958). 71. H. W. Morgan, P. A. Staats agd J. H. Goldstein, J. Client. , 25, 337 (1956). 72. A. H. Nielsen, T. G. Burke, P. J. H. Woltz and E. A. Jones, J. Chem. , 20, 596 (1352). 73. R. R. Patty and R. T. Lagemann, S9ectrochim. Acta, A15, 60 (1959). 73a. H. C. Urey and C. A. Bradley, Phys. , 38, 1969 (1931). 74. T. Shimanouchi, J. Chem. , 17, 245 (1949); Y. Morino, K. Kuchitsu and T. Shimanouchi, J . Chem. , 20, 726 (1952).

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Acyl Halides (1972)


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